PICRIC ACID

PRODUCT IDENTIFICATION

CAS NO. 88-89-1

PICRIC ACID

EINECS NO. 201-865-9
FORMULA C6H2(NO2)3OH
MOL WT. 229.11

H.S. CODE

 

SMILES

phenol

TOXICITY

 
SYNONYMS 2,4,6-Trinitrophenol; 2-Hydroxy-1,3,5-trinitrobenzene;
Pikrinsäure (German); ácido picrico (Spanish); Acide picrique (French); Carbazotic Acid; C.I. 10305; Lyddite; Melinite; Pertite; phenol trinitrate; Picronitric acid; Trinitrophenol;

CLASSIFICATION

 

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE

yellow paste

MELTING POINT

121 - 123 C
BOILING POINT 300 C
SPECIFIC GRAVITY 1.763

SOLUBILITY IN WATER

1.40 g/100 ml (Soluble in most organic solvents)
pH  
VAPOR DENSITY  

AUTOIGNITION

 

NFPA RATINGS

 

REFRACTIVE INDEX

 
FLASH POINT

150 C

STABILITY Stable under ordinary conditions

APPLICATIONS

Picric acid, 2,4,6-trinitrophenol, is a toxic, explosive, highly oxidative yellow crystalline solid with bitter taste; soluble in water, alcohol, chloroform, most organic solvents, and ether; melts at 122 C; derived from phenol through nitration reaction or from chlorobenzene through several steps. Picric acid itself as well as its metallic salts are highly explosive. Lyddite and melinite, high explosives, are composed mostly of compressed or fused picric acid. It is also used as a booster for other explosives and rocket fuel. It should be transported with 30% or more water. In addition to pyrotechnic application, picric acid is used to make dyes (yellow color), antiseptic agents, external medicines, insecticides (chloropicrin, nitrotrichloromethane), batteries and etching copper as well as a colorimetric reagent to determine creatinine.
SALES SPECIFICATION

APPEARANCE

yellow paste

ASSAY (DRY BASIS)

99.0% min

MELTING POINT

121 - 123 C

FREE ACID

0.05% max

WATER

30.0% min

TRANSPORTATION
PACKING 25kgs in drum
HAZARD CLASS 4.1 (Packing Group:I)
UN NO. 0154; 1344
REMARKS
Hazard Symbols: E T, Risk Phrases: 2-4-23/24/25, Safety Phrases: 28-35-37-45