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PICRIC ACID
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PRODUCT IDENTIFICATION |
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CAS NO. | 88-89-1 |
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EINECS NO. | 201-865-9 | |
FORMULA | C6H2(NO2)3OH | |
MOL WT. | 229.11 | |
H.S. CODE |
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SMILES |
phenol |
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TOXICITY |
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SYNONYMS | 2,4,6-Trinitrophenol; 2-Hydroxy-1,3,5-trinitrobenzene; | |
Pikrinsäure (German); ácido picrico (Spanish); Acide picrique (French); Carbazotic Acid; C.I. 10305; Lyddite; Melinite; Pertite; phenol trinitrate; Picronitric acid; Trinitrophenol; | ||
CLASSIFICATION |
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PHYSICAL AND CHEMICAL PROPERTIES |
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PHYSICAL STATE |
yellow paste | |
MELTING POINT |
121 - 123 C | |
BOILING POINT | 300 C | |
SPECIFIC GRAVITY | 1.763 | |
SOLUBILITY IN WATER |
1.40 g/100 ml (Soluble in most organic solvents) | |
pH | ||
VAPOR DENSITY | ||
AUTOIGNITION |
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NFPA RATINGS |
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REFRACTIVE INDEX |
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FLASH POINT |
150 C | |
STABILITY | Stable under ordinary conditions | |
APPLICATIONS |
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Picric acid, 2,4,6-trinitrophenol, is a toxic, explosive, highly oxidative yellow crystalline solid with bitter taste; soluble in water, alcohol, chloroform, most organic solvents, and ether; melts at 122 C; derived from phenol through nitration reaction or from chlorobenzene through several steps. Picric acid itself as well as its metallic salts are highly explosive. Lyddite and melinite, high explosives, are composed mostly of compressed or fused picric acid. It is also used as a booster for other explosives and rocket fuel. It should be transported with 30% or more water. In addition to pyrotechnic application, picric acid is used to make dyes (yellow color), antiseptic agents, external medicines, insecticides (chloropicrin, nitrotrichloromethane), batteries and etching copper as well as a colorimetric reagent to determine creatinine. | ||
SALES SPECIFICATION | ||
APPEARANCE |
yellow paste | |
ASSAY (DRY BASIS) |
99.0% min | |
MELTING POINT |
121 - 123 C | |
FREE ACID |
0.05% max | |
WATER |
30.0% min | |
TRANSPORTATION | ||
PACKING | 25kgs in drum | |
HAZARD CLASS | 4.1 (Packing Group:I) | |
UN NO. | 0154; 1344 | |
REMARKS | ||
Hazard
Symbols: E T, Risk Phrases: 2-4-23/24/25, Safety Phrases: 28-35-37-45
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